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Light Stability Characteristics
All polyethylenes are susceptible to degradation upon long-term exposure
to sunlight. This deterioration is brought about by chemical changes which
occur in the polyethylene as a result of exposure to the ultraviolet (UV)
portion of light. Degradation results in the polyethylene becoming
embrittled, reduc-ing the impact resistance and elongational properties
of the part. Degradation from UV light can be effectively inhibited by the
addition of UV stabilizers, which protect the polyethylene through
preferentially absorbing, transferring or reflecting UV energy.
The UV life of a part is dependent upon UV additive level and type as well
as part thickness and design, pigment type, level and effectiveness of
dispersion, processing conditions and the geographic location where the
molded part is used (see Figure 3). It is important when comparing resin
UV performance to ensure that the testing has been done on a consistent
basis. In Figure 1, accelerated weathering data is presented. Generally,
2,000 hours corresponds to 1 year in Florida and 1,400 hours to 1 year in
Southern Canada. Often terms like "UV- 8" are used. UV- 8 means the
material can withstand 8,000 hours in a Xenon Ci- 65 weatherometer. UV- 2
or UV- 4 would mean 2,000 or 4,000 hours respectively. Hence, UV- 8
corresponds to approximately 4 years of continuous outdoor exposure in
Florida.
It is important to understand which weatherometer, i. e. Carbon Arc or
Xenon, was used, as well as the details of how the weatherometer was
run.ASTM D- 2565 is the recognized standard.Testing can be performed using
actual outdoor weathering exposure, such as Florida and Arizona, to
confirm this data. Note Figure 1 uses the industry standard criteria of
when the sample has reached less than 50% of its original break elongation
to determine the end of the test. In most cases useful life of the part
extends beyond this point. All samples in Figure 1 are nonpig-mented as
supplied by Exxon Chemical. The UV performance test data can be found on
our data sheets for each specific grade.
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